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Fluorine The most reactive element in the periodic table

naturvidenskab Halogener
Fluorine Title Image

Fluorine (F) is a chemical element with atomic number 9 and is the most electronegative element in the periodic table. It belongs to the halogens (group 17) and is extremely reactive.

1. Introduction to fluorine

Fluorine has 9 protons, typically 10 neutrons, and 9 electrons. As the lightest halogen, it appears as a pale yellow, toxic gas at room temperature. Fluorine is highly corrosive and reacts violently with most substances – even glass.

2. Physical and chemical properties

Fluorine is a diatomic gas (F₂), which is extremely reactive and electronegative. It attacks many materials, including metals, plastics, and organic compounds.
  • Melting point: –219.6 °C
  • Boiling point: –188.1 °C
  • Highly toxic and corrosive
Fluorine forms salts and compounds called fluorides – e.g., sodium fluoride (NaF) and uranium hexafluoride (UF₆).

3. Isotopes of fluorine

There is one stable natural isotope:
  • Fluorine-19 (¹⁹F): 9 protons and 10 neutrons (100 % natural abundance)
Fluorine-18 (¹⁸F) is a radioactive isotope used in medical imaging (PET scanning).

4. Industrial applications

Fluorine is used in many industries, often in the form of fluorine compounds:
ApplicationDescription
Fluoroplastics (Teflon)Polytetrafluoroethylene (PTFE) is a non-stick, heat-resistant plastic used in e.g., frying pans.
Aluminum productionFluoride compounds are used as electrolytes in aluminum smelters.
Water fluoridation and dental careSmall amounts of fluoride are added to drinking water and toothpaste to strengthen tooth enamel.
Refrigerants and propellantsFluorocarbons have been used in refrigeration systems and spray cans, but many are now phased out due to environmental concerns.

5. Health and safety

Fluorine in pure forms is extremely toxic and should only be handled under controlled conditions. Inhalation of fluorine or fluoride gases can be life-threatening. However, small amounts of fluoride (as in toothpaste) are beneficial for dental hygiene and prevention of cavities. Excess can, however, lead to dental fluorosis – discoloration of the teeth.

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